Sofia has been nominated in the Best Supporting Actress category and will go up against Jacqueline Bisset (Dancing on the Edge), Janet McTeer (White Queen), Hayden Panettiere (Nashville), and Monica Potter (Parenthood).
Rapper Diddy, who is a presenter this year, also gave his social media followers glimpse inside his pre-red carpet routine and proved that beauty grooming is not just for women.
Puffy no more! Diddy posted this picture of his pre-Globes preparations
Sofia Vergara and P Diddy treated fans to a sneak peek of their rather surprising Golden Globe preparations.
While many Hollywood stars have been following strict diets ahead of the red carpet extravaganza, the Modern Family star spent Sunday afternoon snacking on cake.
The curvaceous 41-year-old enjoyed the sweet treat while getting her hair and make-up done.
She posted a snap on WhoSay with the caption: 'Last minute chocolatecake.'
Sweet treat: Sofia Vergara posted this picture onto her WhoSay account ahead of the Golden Globes
He told his fans: 'For the next hour I'm giving a tutorial on how to get ready for the Golden Globes. These here are cucumber patches flown in from Milan. I know it looks crazy, but nobody said perfection was easy. #diddyglobes'.
And Sofia wasn't the only star to make sure she ate before the big night.
Lining her stomach! Emma Roberts enjoyed a
burger before hitting up the red carpet at the Golden Globes on Sunday
and was careful not to smudge her make-up
Recently engaged American Horror Story star Emma Roberts posted a picture of herself enjoying a burger prior to the ceremony.
With heavily made-up eyes, the star posed for a close up of her face, holding an In-N-Out burger to her mouth.
Preparations: Kelly Osbourne got ready for a busy night of judging the style on the red carpet for her job on Fashion Police
Her dangling red earrings and dazzling rings were visible but not her engagement ring.
There was no glimpse of her dress which she only chose on Sunday, the day of the awards.
Stylist Emily Current of Current/Elliot told InStyle.com: 'Emma Roberts is going to wait until the day of Globes because she is in the middle of filming American Horror Story and she is flying in just for the day.
It takes an army: Kelly had a legion of helpers to ensure she was red carpet ready for the big event on Sunday
'It is an opportunity to put your formal wear on and embrace it.'
Meanwhile Fashion Police panellist Kelly Osbourne shared some of the work that goes into getting a star red carpet ready.
With pictures of her legion of helpers to assist her in preparing for the Globes, she ensured she was prepared for her big day.
Starting early: Breaking Bad's Aaron Paul, his
wife Lauren Parsekian and their pals started boozing early by breaking
out the champagne
Breaking Bad's Aaron Paul, nominated for his work on Breaking Bad, his wife Lauren Parsekian and their pals started boozing early by breaking out the champagne.
Aaron shared a picture of the well-dressed group posing beside their SUV in the shadow of the legendary Chateau Marmont hotel as he clutched a bottle of bubbly before setting off for the awards.
Style secret: Newlywed Kaley Cuoco Sweeting shared her style secret, a sensible pair of flats underneath her floral gown
Newlywed Kaley Cuoco Sweeting shared her style secret, a sensible pair of flats underneath her floral gown.
As her dress was bouffant with many different layers, it was easy for the Big Bang Theory star to disguise her footwear.
Touch up: Heidi Klum's daring gown was on display as she got a last minute touch up from her glam squad in the car
Getting started early: The Voice presenter Carson Daly enjoyed some champagne with pals on the carpet
New Girl's Zooey Deschanel showed off her daisy manicure while fellow nominee Julia Louis-Dreyfus joked about how much she was going to eat before the awards.
Tweeting a picture of a table laden with food and champagne, she wrote: 'My plan is to eat all of this and then send someone out to get me a new gown. Stores are open right?'
Heidi Klum's daring gown was on display as she got a last minute touch up from her glam squad in the car before leaving for the Globes while The Voice presenter Carson Daly enjoyed some champagne.
Suited and booted: It's not just the women who
needed a glam squad, Dan Stevens enlisted Nick Hart to kit him out in a
bespoke Spencer Hart suit at the Golden Globes
Magical: Harry Potter actor Tom Felton was surrounded by suits as he chose his favourite design from Spencer Hart
British tailor Spencer Hart decamped to the legendary Chateau Marmont hotel in Hollywood to fit out stars in bespoke British attire.
Among those he dressed were dapper actors Benedict Cumberbatch, Dan Stevens, Alfonso Cuaron, Tom Felton, Rufus Sewell and Jason Statham.
Meanwhile, Rolls Royce provided cars to VIP Spencer Hart attendees for the best of British experience from the hotel to the awards in Beverly Hills.
The Golden Globes are being hosted Tina Fey and Amy Poehler.
Attention to detail: Zooey Deschanel showed off her Golden Globe nails before she hit the red carpet for her big night
New dress? Julia Louis-Dreyfus joked 'My plan is
to eat all of this and then send someone out to get me a new gown.
Stores are open, right?'